Bimodal functionality of highly conductive nanostructured silver film towards improved performance of photosystem I-based graphene photocathode

dc.authoridIzzo, Miriam/0000-0003-4586-610X
dc.authoridharputlu, ersan/0000-0002-2140-9070
dc.authoridUnlu, Cumhur Gokhan/0000-0003-2554-5886
dc.authoridOcakoglu, Kasim/0000-0003-2807-0425
dc.authoridKowalska, Dorota/0000-0002-9994-1075
dc.authoridSzalkowski, Marcin/0000-0002-7514-5875
dc.contributor.authorSzalkowski, Marcin
dc.contributor.authorKiliszek, Malgorzata
dc.contributor.authorHarputlu, Ersan
dc.contributor.authorIzzo, Miriam
dc.contributor.authorUnlu, C. Gokhan
dc.contributor.authorMackowski, Sebastian
dc.contributor.authorOcakoglu, Kasim
dc.date.accessioned2025-03-17T12:27:26Z
dc.date.available2025-03-17T12:27:26Z
dc.date.issued2025
dc.departmentTarsus Üniversitesi
dc.description.abstractWe present the novel design of photosystem I (PSI)-based biosolar cell, whereby conductive transparent electrode materials, such as ITO or FTO, are replaced with glass covered with silver island film. This nanostructured metallic layer combines high electric conductance with enhancing the absorption efficiency of the PSI biocatalyst via the plasmonic effect. We demonstrate strong enhancement of the photocurrent generated in the biohybrid electrode composed of oriented layers of PSI reaction centers due to plasmonic interactions of the PSI fluorophores and redox centres with the conductive silver island film.
dc.description.sponsorshipPolish National Center for Research and Development [DZP/POLTUR-1/50/2016, 5/POLTUR-1/2016]; Scientific and Technological Research Council of Turkiye, TUBITAK [215M389, 123N061/SUNCOCAT]; Poland's National Science Centre, Solar driven chemistry 2 grant (SUNCOCAT) [2022/04/Y/ST4/00107]
dc.description.sponsorshipJK, MK, MI, MS, DK and SM acknowledge the financial support for this work from the Polish National Center for Research and Development (grant no. DZP/POLTUR-1/50/2016, agreement no. 5/POLTUR-1/2016 to JK and SM), while KO, CGU and EH are supported by the Scientific and Technological Research Council of Turkiye, TUBITAK (grant no. 215M389 and 123N061/SUNCOCAT to KO) within the framework of 1st Bilateral Polish-Turkish POLTUR program. Some of this work was supported by Poland's National Science Centre, Solar driven chemistry 2 grant (SUNCOCAT grant no. 2022/04/Y/ST4/00107 to JK) .
dc.identifier.doi10.1016/j.bioelechem.2024.108825
dc.identifier.issn1567-5394
dc.identifier.issn1878-562X
dc.identifier.pmid39342775
dc.identifier.scopus2-s2.0-85205147862
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.bioelechem.2024.108825
dc.identifier.urihttps://hdl.handle.net/20.500.13099/2252
dc.identifier.volume161
dc.identifier.wosWOS:001328250400001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofBioelectrochemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250316
dc.subjectSIF
dc.subjectPSI
dc.subjectBioelectrodes
dc.subjectPhotocurrent generation
dc.subjectNanostructures
dc.titleBimodal functionality of highly conductive nanostructured silver film towards improved performance of photosystem I-based graphene photocathode
dc.typeArticle

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