Impact of Li2O/metal mole ratio on lithium-ion battery anode performance
Yükleniyor...
Dosyalar
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In this study the electrochemical impact of Li2O/metal mole ratio on the cycle life of lithium-ion
battery anode materials is demonstrated. For this purpose, nanostructured layered LiNi1/3Mn1/3Co1/3O2
(LiNMC) and spinel LiMn1.5Ni0.5O4 (LiMNO) materials, traditionally known as cathode materials, are
evaluated as anode materials and compared against their lithium-free versions NMC (Ni:Mn:Co=1:1:1)
and MNO (Mn:Ni=3:1). The Li2O/metal ratio in fully lithiated states are 2.0 for lithium containing
(LiNMC and LiMNO) and 1.3 for lithium-free (NMC and MNO) samples. Battery tests show that
capacity fading of lithium containing samples is 3 to 4 times larger than lithium-free samples. The
differences in the electronic conductivities and voltages profiles of lithium containing and lithium-free
anode materials are suggested to be the origin of such electrochemical disparity.
Açıklama
Anahtar Kelimeler
lithium battery, conversion anode, composite
Kaynak
International Journal of Electrochemical Science
WoS Q Değeri
Scopus Q Değeri
Cilt
13
Sayı
Künye
Kunduracı, M., Ulusoy Ghobadi, T. G. ve Yılmaz, E. (2018). Impact of Li2O/Metal Mole Ratio on Lithium-ion Battery Anode
Performance, International Journal of Electrochemical Science, 13, 5630-5644. Doi: 10.20964/2018.06.16
