Porphyrins and phthalocyanines as biomimetic tools for photocatalytic H2 production and CO2 reduction

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dc.authoridCharalambidis, Georgios/0000-0003-1237-9962
dc.authoridNikoloudakis, Emmanouil/0000-0002-2320-6672
dc.authoridLadomenou, Kalliopi/0000-0002-8508-1369
dc.authoridLopez-Duarte, Ismael/0000-0002-9941-8305
dc.authoridCoutsolelos, Athanassios G./0000-0001-5682-2968
dc.contributor.authorNikoloudakis, Emmanouil
dc.contributor.authorLopez-Duarte, Ismael
dc.contributor.authorCharalambidis, Georgios
dc.contributor.authorLadomenou, Kalliopi
dc.contributor.authorInce, Mine
dc.contributor.authorCoutsolelos, Athanassios G.
dc.date.accessioned2025-03-17T12:25:54Z
dc.date.available2025-03-17T12:25:54Z
dc.date.issued2022
dc.departmentTarsus Üniversitesi
dc.description.abstractThe increasing energy demand and environmental issues caused by the over-exploitation of fossil fuels render the need for renewable, clean, and environmentally benign energy sources unquestionably urgent. The zero-emission energy carrier, H-2 is an ideal alternative to carbon-based fuels especially when it is generated photocatalytically from water. Additionally, the photocatalytic conversion of CO2 into chemical fuels can reduce the CO2 emissions and have a positive environmental and economic impact. Inspired by natural photosynthesis, plenty of artificial photocatalytic schemes based on porphyrinoids have been investigated. This review covers the recent advances in photocatalytic H-2 production and CO2 reduction systems containing porphyrin or phthalocyanine derivatives. The unique properties of porphyrinoids enable their utilization both as chromophores and as catalysts. The homogeneous photocatalytic systems are initially described, presenting the various approaches for the improvement of photosensitizing activity and the enhancement of catalytic performance at the molecular level. On the other hand, for the development of the heterogeneous systems, numerous methods were employed such as self-assembled supramolecular porphyrinoid nanostructures, construction of organic frameworks, combination with 2D materials and adsorption onto semiconductors. The dye sensitization on semiconductors opened the way for molecular-based dye-sensitized photoelectrochemical cells (DSPECs) devices based on porphyrins and phthalocyanines. The research in photocatalytic systems as discussed herein remains challenging since there are still many limitations making them unfeasible to be used at a large scale application before finding a large-scale application.
dc.description.sponsorshipGeneral Secretariat for Research and Technology (GSRT); Hellenic Foundation for Research and Innovation (HFRI) [508]; European Union; Greek national funds through the Regional Operational Program Crete 2014-2020 [OPS: 5029187]; European Commission [229927]; Special Research Account of the University of Crete
dc.description.sponsorshipThis research was funded by the General Secretariat for Research and Technology (GSRT) and Hellenic Foundation for Research and Innovation (HFRI; project code: 508). This research has been co-financed by the European Union and Greek national funds through the Regional Operational Program Crete 2014-2020, project code OPS: 5029187. Moreover, the European Commission's Seventh Framework Program (FP7/2007-2013) under grant agreement no. 229927 (FP7-REGPOT-2008-1, Project BIO-SOLENUTI) and the Special Research Account of the University of Crete are gratefully acknowledged for the financial support.
dc.identifier.doi10.1039/d2cs00183g
dc.identifier.endpage7045
dc.identifier.issn0306-0012
dc.identifier.issn1460-4744
dc.identifier.issue16
dc.identifier.pmid35686606
dc.identifier.scopus2-s2.0-85131718216
dc.identifier.scopusqualityQ1
dc.identifier.startpage6965
dc.identifier.urihttps://doi.org/10.1039/d2cs00183g
dc.identifier.urihttps://hdl.handle.net/20.500.13099/1907
dc.identifier.volume51
dc.identifier.wosWOS:000810130300001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofChemical Society Reviews
dc.relation.publicationcategoryDiğer
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250316
dc.subjectMetal-Organic Framework
dc.subjectGraphitic Carbon Nitride
dc.subjectSoluble Zinc Porphyrin
dc.subjectWater-Splitting System
dc.subjectVisible-Light Photoreduction
dc.subjectInduced Hydrogen Evolution
dc.subjectHighly-Efficient
dc.subjectElectron-Transfer
dc.subjectGraphene Oxide
dc.subjectCobalt Phthalocyanine
dc.titlePorphyrins and phthalocyanines as biomimetic tools for photocatalytic H2 production and CO2 reduction
dc.typeReview

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