Caustic recovery from caustic-containing polyethylene terephthalate (PET) washing wastewater generated during the recycling of plastic bottles
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Tarih
2025
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Nature Portfolio
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
To prevent water scarcity, wastewater must be discharged to the surface or groundwater after being treated. Another method is to reuse wastewater in some areas after treatment and evaluate it as much as possible. In this study, it is aimed to recover and reuse the caustic (sodium hydroxide, NaOH) used in the recycling of plastic bottles from polyethylene terephthalate (PET) washing wastewater. Chemical substances used in the industry will be significantly reduced with chemical recovery from wastewater. Ultrafiltration (UP150) and nanofiltration (NP010 and NP030) membranes were used for this purpose in our study. Before using nanofiltration membranes, pre-treatment was performed with coagulation-flocculation process to reduce the pollutant accumulation on the membranes. Different coagulants and flocculants were used to find suitable coagulants and flocculants in pre-treatment. The pre-treated wastewater using aluminum oxide, which supplied the highest chemical oxygen demand (COD) removal (76.0%), was used in a dead-end filtration system to be filtered through NP010 and NP030 membranes at different pressures (10-30 bar). In the same filtration system, raw wastewater was filtered through a UP150 membrane. Among these treatment scenarios, the best method that could remove pollutants and provide NaOH recovery was selected. After each treatment, pH, conductivity, COD, and NaOH analyses were performed. The maximum NaOH recovery (98.6%) was obtained with the UP150 membrane at 5 bar.
Açıklama
Anahtar Kelimeler
PET washing wastewater, Coagulation-flocculation, Ultrafiltration, Nanofiltration, NaOH recovery, Wastewater recycling
Kaynak
Scientific Reports
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
15
Sayı
1