Subphthalocyanines for Visible-Light-Driven Hydrogen Evolution: Tuning Photocatalytic Performance with Molecular Design
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Tarih
2023
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Amer Chemical Soc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this work, a series of subphthalocyanines (SubPcs)with a carboxylicacid anchoring group at the axial position were used as photosensitizersof TiO2 for photocatalytic hydrogen evolution from waterunder visible light irradiation. SubPc derivatives with various peripheralsubstituents were successfully prepared to systematically investigatethe dependence of photocatalytic performance on electron-donatingunits (i.e., bisthiophene or thioether) at the peripheral positionof the SubPcs. SubPc 2/TiO2/Pt shows the best photocatalyticactivity among the three dye-sensitized photocatalysts, with a hydrogenevolution rate of 1.104 mmol center dot g(-1)center dot h(-1). After 24 h irradiation, SubPc 2/TiO2/Ptachieved a remarkable catalytic activity for the production of H-2 (19.96 mmol center dot g(-1)) with a TON valueof 40 734 and a high STH efficiency of 2.1%. Density functionaltheory (DFT) and time-dependent DFT (TD-DFT) approaches were usedto elucidate further structural and electrical properties, includingthe interaction patterns of tailored SubPcs. It is worth noting thatthe theoretical computations exhibit good conformity with the empiricaldata. The predicted fluctuations in photocatalytic activity detectedin SubPc systems were shown to be closely associated with frontiermolecular orbital (FMO) characteristics, noncovalent interaction (NCI)patterns, and the electron-donating nature of the fragments locatedat the peripheral positions.
Açıklama
Anahtar Kelimeler
photocatalytic hydrogen, subphthalocyanine, dye sensitizer, density functional theory, artificialphotosynthesis
Kaynak
Acs Applied Energy Materials
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
6
Sayı
12
