Combustion Characteristics of r-GO/g-C3N4/LaFeO3 Nanohybrids Loaded Fuel Droplets

dc.authoridhttps://orcid.org/0000-0002-5453-5137
dc.authoridhttps://orcid.org/0000-0003-2807-0425
dc.authorscopusid57218339719
dc.authorscopusid58018058200
dc.authorscopusid57224482924
dc.authorscopusid57192061229
dc.authorscopusid55348334900
dc.authorscopusid36088420200
dc.authorwosidAAM-8078-2020
dc.authorwosidIVV-2642-2023
dc.authorwosidQ-8088-2017
dc.authorwosidDZH-7327-2022
dc.contributor.authorKüçükosman, Rıdvan
dc.contributor.authorDeğirmenci, Hüseyin
dc.contributor.authorSert, Buse
dc.contributor.authorYontar, Ahmet Alper
dc.contributor.authorHarputlu, Ersan
dc.contributor.authorOcakoğlu, Kasım
dc.date.accessioned2023-12-01T09:03:46Z
dc.date.available2023-12-01T09:03:46Z
dc.date.issued2023
dc.departmentFakülteler, Mühendislik Fakültesi, Makine Mühendisliği Bölümü
dc.description.abstractGraphene oxide (GO), reduced graphene oxide (r-GO) and graphitic carbon nitride (g-C3N4) are two-dimensional carbon-based nanosheets that show promise in reducing emissions with their superior catalytic activity in capturing species such as NOx and CO2 thanks to their oxygen- based functional groups and active edges on their surfaces. These active surfaces also provide a scheme for the substitution of materials with high calorific value or high catalytic activity for combustion. This study focuses on the fabrication of functional nanohybrid structures customized for combustion with LaFeO3 metal oxide nanoparticles substituted on these nanosheets and their effect on the combustion behavior of gaso-line. The fabrication of r-GO/g-C3N4/LaFeO3 nanohybrid structures was carried out by a two-step hydrothermal method. The structural character-izations of the samples were confirmed by SEM and XRD analyses and their chemical states were confirmed by Raman and XPS techniques. Combustion experiments were carried out by droplet scale combustion of gasoline-based nanofuel droplets containing dilute (0.2 wt.%) and high (0.7 wt.%) concentrations of GO, r-GO, g-C3N4, g-C3N4/LaFeO3 and r-GO/g- C3N4/LaFeO3 nanoparticles. The experimental process was recorded with a high-speed camera and a thermal camera. The nanofuel droplets con-taining 0.2 wt.% g-C3N4/LaFeO3 nanohybrid structures had the highest maximum flame temperature of 519 K, and the nanofuel droplets con-taining 0.7 wt.% r-GO/g-C3N4/LaFeO3 particles had the highest maximum aggregate temperature of 1177 K. The ignition delay time decreased for all droplets with 0.2 wt.% and 0.7 wt.% particle loadings. At 0.2 wt.% concentration, g-C3N4 doped fuel droplets exhibited the lowest extinction time, while at 0.7 wt.% concentration, the lowest extinction time was measured for r-GO/g-C3N4/LaFeO3 doped fuel droplets. Fuel droplets containing g-C3N4 particles had the highest burning rate and were the fastest extinguishing fuel droplets in the electric field. In this study, it has been demonstrated that the combustion rate and energy value of hydro-carbon fuels can be increased and soot formation can be reduced at the same time with the new generation of graphene-based functional mate-rials to be created, and thus, many combustion problems can be solved simultaneously with these functional particles.
dc.identifier.citationKüçükosman R., Değirmenci H., Sert B., Yontar A.A., Harputlu E. ve Ocakoglu K. (2023).Combustion Characteristics of r-GO/g-C3N4/LaFeO3 Nanohybrids Loaded Fuel Droplets. Combustion Science and Technology, 1-36. doi:10.1080/00102202.2023.2280609
dc.identifier.doi10.1080/00102202.2023.2280609
dc.identifier.endpage36en_US
dc.identifier.issn0010-2202
dc.identifier.scopus2-s2.0-85176594819
dc.identifier.scopusqualityQ2
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1080/00102202.2023.2280609
dc.identifier.urihttps://hdl.handle.net/20.500.13099/185
dc.identifier.wosWOS:001103860300001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakScopus
dc.institutionauthorKüçükosman, Rıdvan
dc.institutionauthorDeğirmenci, Hüseyin
dc.institutionauthorSert, Buse
dc.institutionauthorYontar, Ahmet Alper
dc.institutionauthorHarputlu, Ersan
dc.institutionauthorOcakoğlu, Kasım
dc.language.isoen
dc.publisherTaylor and Francis Ltd.
dc.relation.ispartofCombustion Science and Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectgraphene
dc.subjectgraphitic carbon nitride
dc.subjectNanohybrids
dc.subjectperovskite oxide
dc.subjectreduced graphene oxide
dc.subjectCarbon nitride
dc.subjectCatalyst activity
dc.subjectGasoline
dc.subjectGraphene
dc.subjectHigh speed cameras
dc.subjectIgnition
dc.subjectIron compounds
dc.subjectMetal nanoparticles
dc.subjectMethane
dc.subjectNanosheets
dc.subjectNanostructured materials
dc.subjectPerovskite
dc.subjectCombustion characteristics
dc.subjectExtinction time
dc.subjectFuel droplets
dc.subjectGraphene oxides
dc.subjectGraphitic carbon nitrides
dc.subjectNanofuel
dc.subjectNanohybrids
dc.subjectPerovskite oxides
dc.subjectReduced graphene oxides
dc.subjectTwo-dimensional
dc.subjectLanthanum compounds
dc.titleCombustion Characteristics of r-GO/g-C3N4/LaFeO3 Nanohybrids Loaded Fuel Droplets
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Yükleniyor...
Küçük Resim
İsim:
ocakoglu, kasım.png
Boyut:
230.18 KB
Biçim:
Portable Network Graphics
Açıklama:
Makale Dosyası
Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama: