Study of the local structure and electrical properties of gallium substituted LLZO electrolyte materials

Basit Öğe Kaydı
dc.authoridAtes, Sule/0000-0001-9324-6808
dc.authoridATAV, ULFET/0000-0002-2367-6666
dc.authoridSaran, Sevda/0000-0002-2647-0700
dc.authoridEker, Yasin Ramazan/0000-0001-7395-4364
dc.authoridOzkendir, Osman Murat/0000-0002-0810-9938
dc.authoridCELIK, GULTEKIN/0000-0001-8587-322X
dc.contributor.authorAktas, Sevda
dc.contributor.authorOzkendir, Osman Murat
dc.contributor.authorEker, Yasin Ramazan
dc.contributor.authorAtes, Sule
dc.contributor.authorAtav, Ulfet
dc.contributor.authorCelik, Gultekin
dc.contributor.authorKlysubun, Wantana
dc.date.accessioned2025-03-17T12:27:05Z
dc.date.available2025-03-17T12:27:05Z
dc.date.issued2019
dc.departmentTarsus Üniversitesi
dc.description.abstractThe solid-state lithium batteries are more stable than the batteries with liquid electrolyte, however their performance are also worse especially due to the low ionic conduction of their electrolyte. Garnet-type Li7La3Zr2O12 is a promising solid-state electrolyte candidate for lithium batteries. In this work the influence of gallium substitution on the electrical, crystal and electronic structure properties in the Li7La3Zr2O12 material were studied. Li7-3xGaxLa3Zr2O12 solid electrolytes were synthesized by solid state reaction method and characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), AC impedance spectroscopy and X-ray absorption spectroscopy (XAS) techniques. XRD and XAS analyses showed that the x = 0.05 sample is formed in the tetragonal phase with a space group of I4(1)/ acd:2 and the rest are formed in the cubic phase with a space group of I-43d due to strong coupling between outer shell electrons of the oxygen (O) and gallium (Ga) atoms. Electrochemical impedance spectroscopy (EIS) studies indicated that the tetragonal phase has the highest ionic conductivity, 3.04 x 10(-6) S cm(-1), among all other cubic phases. (C) 2019 Published by Elsevier B.V.
dc.description.sponsorshipSelcuk University Scientific Research Projects (BAP) Coordinating Office (Konya, Turkey) [17101004]
dc.description.sponsorshipThe authors gratefully acknowledge the financial support of 17101004 project of Selcuk University Scientific Research Projects (BAP) Coordinating Office (Konya, Turkey).
dc.identifier.doi10.1016/j.jallcom.2019.04.049
dc.identifier.endpage285
dc.identifier.issn0925-8388
dc.identifier.issn1873-4669
dc.identifier.scopus2-s2.0-85063948308
dc.identifier.scopusqualityQ1
dc.identifier.startpage279
dc.identifier.urihttps://doi.org/10.1016/j.jallcom.2019.04.049
dc.identifier.urihttps://hdl.handle.net/20.500.13099/2068
dc.identifier.volume792
dc.identifier.wosWOS:000467235800032
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Alloys and Compounds
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250316
dc.subjectGarnet type solid electrolytes
dc.subjectImpedance spectroscopy
dc.subjectX-ray absorption fine structure
dc.titleStudy of the local structure and electrical properties of gallium substituted LLZO electrolyte materials
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu